Jump to main content
Jump to site search

Issue 16, 2017
Previous Article Next Article

Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones

Author affiliations

Abstract

The reaction of tetraalkynyltin with aldehydes was studied for the first time. The reaction was shown to proceed as a tandem process of nucleophilic addition of tin acetylide to aldehyde followed by Oppenauer-type oxidation of produced tin alcoholates, and may be used as a convenient one-pot approach to acetylenic ketones. The advantages and limitations of the proposed method are discussed.

Graphical abstract: Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones

Back to tab navigation

Supplementary files

Publication details

The article was received on 25 Apr 2017, accepted on 30 Jun 2017 and first published on 30 Jun 2017


Article type: Paper
DOI: 10.1039/C7NJ01376K
Citation: New J. Chem., 2017,41, 8297-8304
  • Open access: Creative Commons BY-NC license
  •   Request permissions

    Oxidative coupling of tetraalkynyltin with aldehydes leading to alkynyl ketones

    A. S. Levashov, N. A. Aksenov, I. V. Aksenova and V. V. Konshin, New J. Chem., 2017, 41, 8297
    DOI: 10.1039/C7NJ01376K

    This article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence. Material from this article can be used in other publications provided that the correct acknowledgement is given with the reproduced material and it is not used for commercial purposes.

    Reproduced material should be attributed as follows:

    • For reproduction of material from NJC:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the Centre National de la Recherche Scientifique (CNRS) and the RSC.
    • For reproduction of material from PCCP:
      [Original citation] - Published by the PCCP Owner Societies.
    • For reproduction of material from PPS:
      [Original citation] - Published by The Royal Society of Chemistry (RSC) on behalf of the European Society for Photobiology, the European Photochemistry Association, and RSC.
    • For reproduction of material from all other RSC journals:
      [Original citation] - Published by The Royal Society of Chemistry.

    Information about reproducing material from RSC articles with different licences is available on our Permission Requests page.

Search articles by author

Spotlight

Advertisements