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Issue 16, 2017
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Highly selective oxidation of methanol to dimethoxymethane over SO42−/V2O5–ZrO2

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Abstract

The sulfated vanadia–zirconia SO42−/V2O5–ZrO2 catalyst, prepared by an impregnation method and calcined at various temperatures, was found to have a high catalytic activity for methanol oxidation to dimethoxymethane in a fixed bed reactor and a batch autoclave using O2 as the oxidant due to the crystalline V2O5 dispersed on the surface as redox active sites, as well as stronger acidic sites.

Graphical abstract: Highly selective oxidation of methanol to dimethoxymethane over SO42−/V2O5–ZrO2

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Publication details

The article was received on 19 Apr 2017, accepted on 07 Jul 2017 and first published on 07 Jul 2017


Article type: Paper
DOI: 10.1039/C7NJ01295K
Citation: New J. Chem., 2017,41, 8370-8376
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    Highly selective oxidation of methanol to dimethoxymethane over SO42−/V2O5–ZrO2

    M. Tao, H. Wang, Bin Lu, J. Zhao and Q. Cai, New J. Chem., 2017, 41, 8370
    DOI: 10.1039/C7NJ01295K

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