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Issue 16, 2017
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Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

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Abstract

Electron precise [Mo33-S)(μ-S)3(diphos)3Br3]Br (diphos = dppe, dmpe) incomplete cuboidal clusters with six cluster skeletal electrons (CSE) were converted into paramagnetic cuboidal [Mo3(GaBr)(μ3-S)4(diphos)3Br3] clusters by treatment with elemental Ga. The new heterobimetallic complexes with nine CSE possess a doublet ground state with the unpaired electron density delocalized over the three molybdenum atoms.

Graphical abstract: Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

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Publication details

The article was received on 12 Apr 2017, accepted on 04 Jul 2017 and first published on 05 Jul 2017


Article type: Letter
DOI: 10.1039/C7NJ01217A
Citation: New J. Chem., 2017,41, 7849-7852
  • Open access: Creative Commons BY-NC license
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    Synthesis, molecular structures and EPR spectra of the paramagnetic cuboidal clusters with Mo3S4Ga cores

    P. A. Petrov, D. Yu. Naumov, T. S. Sukhikh, S. N. Konchenko, C. J. Gómez-García and R. Llusar, New J. Chem., 2017, 41, 7849
    DOI: 10.1039/C7NJ01217A

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