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Issue 22, 2017
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Both end-on and end-to-end azide bridged tetranuclear ferromagnetic nickel(II) Schiff base complexes

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Abstract

Variable temperature magnetic measurements of a novel tetranuclear nickel(II) complex, consisting of two pseudo-dinuclear entities bridged by an end-to-end azide, indicate the presence of both intra- and inter-dinuclear ferromagnetic interactions (J1 = 16.48 cm−1 and J2 = 24.17 cm−1, respectively), as also corroborated by DFT calculations (J1 = 12.0 cm−1 and J2 = 29.2 cm−1).

Graphical abstract: Both end-on and end-to-end azide bridged tetranuclear ferromagnetic nickel(ii) Schiff base complexes

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Publication details

The article was received on 16 Mar 2017, accepted on 08 Sep 2017 and first published on 11 Sep 2017


Article type: Paper
DOI: 10.1039/C7NJ00852J
Citation: New J. Chem., 2017,41, 13585-13592
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    Both end-on and end-to-end azide bridged tetranuclear ferromagnetic nickel(II) Schiff base complexes

    A. Bhattacharyya, M. Das, A. Bauzá, S. Herrero, R. González-Prieto, A. Frontera and S. Chattopadhyay, New J. Chem., 2017, 41, 13585
    DOI: 10.1039/C7NJ00852J

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