Jump to main content
Jump to site search

Issue 12, 2017
Previous Article Next Article

Role of crystallization water molecules on hydrogen-bonded structures and dielectric phase transitions in amino trimethylene phosphonic acid-based crystals

Author affiliations

Abstract

Three hydrogen-bonded organic salts (HTBA)2(H4ATMP)·(H2O)3 (1), (HTBA)6(H3O)(H2.5ATMP)2·(H2O)2 (2) and (HTBA)6(H3ATMP)2·H2O (3) were synthesized by combining different molar ratios of amino trimethylene phosphonic acid (H6ATMP) and tert-butylamine (TBA). There are three-dimensional hydrogen-bonded networks in 1–3. The crystallization water molecules that are loosely trapped in the supramolecular hydrogen-bonded networks in 1 and 2 undergo order–disorder transitions whose dynamic changes are likely to be responsible for dielectric transitions and relaxations.

Graphical abstract: Role of crystallization water molecules on hydrogen-bonded structures and dielectric phase transitions in amino trimethylene phosphonic acid-based crystals

Back to tab navigation

Supplementary files

Publication details

The article was received on 21 Feb 2017, accepted on 12 May 2017 and first published on 15 May 2017


Article type: Paper
DOI: 10.1039/C7NJ00612H
Citation: New J. Chem., 2017,41, 5142-5150
  •   Request permissions

    Role of crystallization water molecules on hydrogen-bonded structures and dielectric phase transitions in amino trimethylene phosphonic acid-based crystals

    Y. Sun, B. Zheng and W. Zhang, New J. Chem., 2017, 41, 5142
    DOI: 10.1039/C7NJ00612H

Search articles by author

Spotlight

Advertisements