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Addition of N-nucleophiles to gold(III)-bound isocyanides leading to short-lived gold(III) acyclic diaminocarbene complexes

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Abstract

Reaction of [AuCl3(CNR1)] (R1 = Xyl, Cy, (S)-CHMePh) with amines unexpectedly proceeds via the redox pathway giving gold(I)–isocyanides and imines, while the addition of benzophenone hydrazone to the isocyanide ligand in [AuCl3(CNR1)] at RT leads to short-lived gold(III) acyclic diaminocarbene complexes [AuCl3{C(NHNCPh2)NHR1}].

Graphical abstract: Addition of N-nucleophiles to gold(iii)-bound isocyanides leading to short-lived gold(iii) acyclic diaminocarbene complexes

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Supplementary files

Publication details

The article was received on 13 Feb 2017, accepted on 03 Apr 2017 and first published on 06 Apr 2017


Article type: Letter
DOI: 10.1039/C7NJ00529F
Citation: New J. Chem., 2017, Advance Article
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    Addition of N-nucleophiles to gold(III)-bound isocyanides leading to short-lived gold(III) acyclic diaminocarbene complexes

    T. B. Anisimova, M. A. Kinzhalov, M. F. C. Guedes da Silva, A. S. Novikov, V. Yu. Kukushkin, A. J. L. Pombeiro and K. V. Luzyanin, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00529F

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