Jump to main content
Jump to site search


MCM-41-supported phosphotungstic acid-catalyzed cleavage of C–O bond in allyl aryl ethers

Author affiliations

Abstract

Removal of the protecting allyl group from allyl aryl ethers in the presence of other oxygen protecting groups was successfully achieved using a solid acid supported on the high surface area material MCM-41. The catalyst showed excellent activity in the presence of various electron withdrawing, electron donating, and oxidizable functional groups. The methodology is also very useful for the removal of protecting allyl groups of various natural products such as vanillin, isovanillin, and other oxygen functionalized aldehydes and ketones.

Graphical abstract: MCM-41-supported phosphotungstic acid-catalyzed cleavage of C–O bond in allyl aryl ethers

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 31 Jan 2017, accepted on 10 May 2017 and first published on 11 May 2017


Article type: Paper
DOI: 10.1039/C7NJ00375G
Citation: New J. Chem., 2017, Advance Article
  •   Request permissions

    MCM-41-supported phosphotungstic acid-catalyzed cleavage of C–O bond in allyl aryl ethers

    S. S. Sakate, S. B. Kamble, R. C. Chikate and C. V. Rode, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00375G

Search articles by author