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Synthesis of crystalline molybdenum oxides based on a 1D molecular structure and their ion-exchange properties

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Abstract

The development of new materials for ion-exchange applications is interesting and important. A crystalline material based on an anionic telluromolybdate molecular wire, Mo-Te-O, was carefully synthesized, and it exhibits unique ion-exchange properties. On the one hand, NH4+ is exchanged with alkaline metal ions. Cs+, as radiation waste in nuclear wastewater, can be selectively removed rapidly and efficiently. On the other hand, because of the flexible crystal structure, large organoammonium cations are incorporated in the structure of the material by ion-exchange. After ion-exchange, the molecular wire building block becomes stable.

Graphical abstract: Synthesis of crystalline molybdenum oxides based on a 1D molecular structure and their ion-exchange properties

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Publication details

The article was received on 28 Jan 2017, accepted on 25 Apr 2017 and first published on 25 Apr 2017


Article type: Paper
DOI: 10.1039/C7NJ00334J
Citation: New J. Chem., 2017, Advance Article
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    Synthesis of crystalline molybdenum oxides based on a 1D molecular structure and their ion-exchange properties

    Q. Zhu, Z. Zhang, M. Sadakane, A. Yoshida, M. Hara and W. Ueda, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00334J

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