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New lead(II) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16

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Abstract

Through systematic research on the PbO/PbF2/H3BO3 ternary phase diagram, two new lead(II) borates, β-Pb6B10O21 and Pb4B8O16, were synthesized by a high temperature solution method. The polymerization degree of the B–O network was analyzed with increasing B : Pb ratio.

Graphical abstract: New lead(ii) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16

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Publication details

The article was received on 17 Jan 2017, accepted on 28 Mar 2017 and first published on 29 Mar 2017


Article type: Paper
DOI: 10.1039/C7NJ00203C
Citation: New J. Chem., 2017, Advance Article
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    New lead(II) borates in the PbO/PbF2/H3BO3 ternary phase diagram: syntheses and structures of β-Pb6B10O21 and Pb4B8O16

    L. Dong, L. Jia and L. Wang, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00203C

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