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‘One-pot’synthesis and redox evaluations of chiral chalcogenocysteinol and β-bis-chalcogenoamine derivatives from L-Serine Methyl Ester

Abstract

The synthesis of a new class of chiral chalcogenocysteinols and bis-chalcogenoamines is described in this study. Compounds were prepared from commercially available L-serine using simple reactions to obtain the desired products. Additionally, compounds were evaluated for potential antioxidant applications by cyclic voltammetry and showed to have appropriate electrochemical oxidation potential. Density functional theory (DFT) calculations were used to better characterize oxidative sites in the bis-chalcogenoamines, giving theoretical support to the experimental findings.

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Publication details

The article was received on 16 Jan 2017, accepted on 19 Jun 2017 and first published on 19 Jun 2017


Article type: Paper
DOI: 10.1039/C7NJ00194K
Citation: New J. Chem., 2017, Accepted Manuscript
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    ‘One-pot’synthesis and redox evaluations of chiral chalcogenocysteinol and β-bis-chalcogenoamine derivatives from L-Serine Methyl Ester

    P. Foletto, L. Dornelles, B. A. Iglesias, A. D. C. Bevilacqua, P. C. Piquini and O. E. D. Rodrigues, New J. Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7NJ00194K

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