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A Jack of Trio”-robust one-pot metal free oxidative amination, azidation and peroxidation of phenols

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Abstract

Herein we disclose a highly efficient methodology for the generation of nitrogen containing quaternary carbon centres via aminative and azidative oxidative dearomatization of phenols. The same protocol has also been successfully employed to achieve oxidative peroxidation of phenols. The simplest metal free reaction conditions delineate an easy breakthrough to the “Trio”- oxidative amination, azidation and peroxidation. An array of diverse polyfunctionalised heterocycles has been synthesized in one pot.

Graphical abstract: “A Jack of Trio”-robust one-pot metal free oxidative amination, azidation and peroxidation of phenols

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Publication details

The article was received on 14 Jan 2017, accepted on 07 Apr 2017 and first published on 07 Apr 2017


Article type: Letter
DOI: 10.1039/C7NJ00169J
Citation: New J. Chem., 2017, Advance Article
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    A Jack of Trio”-robust one-pot metal free oxidative amination, azidation and peroxidation of phenols

    D. Sarkar, M. K. Ghosh, N. Rout and P. Kuila, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00169J

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