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Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates

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Abstract

New antimony-capped iron and nickel(II) tris-pyridineoximates with a labile triethylantimony cross-linking group were obtained by template condensation of 2-acetylpyridinoxime with triethylantimony(V) dibromide on the corresponding metal ion as a matrix. They easily undergo transmetallation (capping group exchange) with Lewis-acidic zirconium and hafnium(IV) phthalocyaninates (Pc) to give binuclear MPc-capped tris-pyridineoximates. The obtained hybrid complexes and their precursors were thoroughly characterized (among others, by single-crystal X-ray diffraction), and their redox properties were studied by cyclic and differential pulse voltammetry.

Graphical abstract: Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates

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Publication details

The article was received on 11 Jan 2017, accepted on 06 Mar 2017 and first published on 10 Mar 2017


Article type: Paper
DOI: 10.1039/C7NJ00131B
Citation: New J. Chem., 2017, Advance Article
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    Synthesis, X-ray structure and electrochemical properties of hybrid binuclear metallophthalocyaninate-capped tris-pyridineoximates

    S. V. Dudkin, A. S. Belov, Y. V. Nelyubina, A. V. Savchuk, A. A. Pavlov, V. V. Novikov and Y. Z. Voloshin, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00131B

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