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Hypercrosslinked conjugated microporous polymers for carbon capture and energy storage

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Abstract

Three hypercrosslinked conjugated microporous polymers were prepared using Friedel–Crafts reaction based on tetraphenylporphyrin, triphenylamine and tetraphenylmethane with p-dimethoxybenzene as an external crosslinker. The polymers show large surface areas (921 m2 g−1) and CO2 uptake capacity (12.3 wt%). Due to its π-conjugated structure, the tetraphenylporphyrin based polymer (HCTPP) shows high specific capacitance (179 F g−1). Considering their large surface area, high gas uptake capacity, good specific capacitance and facile synthesis method, these materials are promising candidates for carbon capture and energy storage.

Graphical abstract: Hypercrosslinked conjugated microporous polymers for carbon capture and energy storage

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Publication details

The article was received on 09 Jan 2017, accepted on 13 Apr 2017 and first published on 17 Apr 2017


Article type: Paper
DOI: 10.1039/C7NJ00105C
Citation: New J. Chem., 2017, Advance Article
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    Hypercrosslinked conjugated microporous polymers for carbon capture and energy storage

    X. Jiang, Y. Liu, J. Liu, X. Fu, Y. Luo and Y. Lyu, New J. Chem., 2017, Advance Article , DOI: 10.1039/C7NJ00105C

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