Jump to main content
Jump to site search


A Green Direct Preparation of a Magnetic Ordered Mesoporous Carbon Catalyst Containing Fe-Pd Alloys. Application to Suzuki-Miyaura Reactions in Propane-1,2-diol

Abstract

We report here a direct one-pot environmentally-friendly preparation of a magnetic mesoporous carbon containing Fe-Pd alloys from easily accessible and cheap biosourced tannin as a carbon precursor, Pluronic F127 surfactant as a pore structuring agent, PdCl2 and Fe(NO3)3. This catalyst was successfully used for Suzuki-Miyaura reactions in the presence of extremely low amounts of supported Pd (150 microequiv.) in a non-toxic solvent (propane-1,2-diol). The catalyst can be recovered quantitatively by simple application of an external magnetic field and biaryls containing < 1.5 microequiv. of Pd (i.e. < 1 ppm) are obtained without any additional purification steps.

Back to tab navigation
Please wait while Download options loads

Supplementary files

Publication details

The article was received on 03 Jan 2017, accepted on 05 May 2017 and first published on 09 May 2017


Article type: Paper
DOI: 10.1039/C7NJ00030H
Citation: New J. Chem., 2017, Accepted Manuscript
  •   Request permissions

    A Green Direct Preparation of a Magnetic Ordered Mesoporous Carbon Catalyst Containing Fe-Pd Alloys. Application to Suzuki-Miyaura Reactions in Propane-1,2-diol

    C. Peter, A. Derible, J. Parmentier, C. Le Drian and J. Becht, New J. Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7NJ00030H

Search articles by author