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Issue 9, 2017
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First structural evidence of a Se–Br–Br halogen-bonded molecular complex

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Abstract

The halogenation of 2,6-dibromo-9-selenabicyclo[3.3.1]-nonane 1 with 1 equivalent of molecular dihalogens (Br2 and I2) afforded a 1 : 1 molecular complex 1–X2 (X = Br (2); X = I (3)), while an excess of Br2 resulted in the ionic species [C8H12Br2SeBr]Br5 (4). X-ray crystallographic data and the nature of Se⋯Br non-covalent bonding in the solid state and solution is discussed.

Graphical abstract: First structural evidence of a Se–Br–Br halogen-bonded molecular complex

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Publication details

The article was received on 27 Dec 2016, accepted on 28 Mar 2017 and first published on 31 Mar 2017


Article type: Paper
DOI: 10.1039/C6NJ04096A
Citation: New J. Chem., 2017,41, 3606-3611
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    First structural evidence of a Se–Br–Br halogen-bonded molecular complex

    Y. V. Torubaev, I. V. Skabitskiy, A. V. Pavlova and A. A. Pasynskii, New J. Chem., 2017, 41, 3606
    DOI: 10.1039/C6NJ04096A

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