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Highly active Ni-Fe double hydroxides as anode catalysts for electrooxidation of urea

Abstract

Urea is a safe and sustainable chemical for electrochemical energy conversion and storage. However, the sluggish kinetic rates of the urea electrooxidation reaction as well as catalyst stability still remain challenges. In this work, we investigated several catalysts for electro-oxidation of urea by directly growing NiM double hydroxides (M=Cr, Mn, Fe, Co, Cu, Zn) on carbon fibre cloth and nickel foam electrodes through a facile one-step hydrothermal synthesis method. The results indicated that the activity was significantly related to the elements composition. Among the investigated double hydroxides, the NiFe double hydroxides (DH) catalyst showed the highest activity, which achieved a specific current density of ~95 mA cm-2 mg-1 at 0.5 V vs. Ag/AgCl, about 10 times larger than that of Ni(OH)2. In addition, the NiFe DH also had a high activity when grown on a Ni foam substrate. This NiFe DH performs well in the aspect of urea oxidation stability, demonstrating it to be a promising low-cost and stable catalyst for efficient urea electrooxidation in alkaline conditions.

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Publication details

The article was received on 23 Dec 2016, accepted on 18 Apr 2017 and first published on 18 Apr 2017


Article type: Paper
DOI: 10.1039/C6NJ04060H
Citation: New J. Chem., 2017, Accepted Manuscript
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    Highly active Ni-Fe double hydroxides as anode catalysts for electrooxidation of urea

    W. Xu, D. Du, R. Lan, J. Humphreys, Z. WU and S. Tao, New J. Chem., 2017, Accepted Manuscript , DOI: 10.1039/C6NJ04060H

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