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Synthesis and self-assembly of a D3h symmetric polycyclic aromatic hydrocarbon into a rigid 2D honeycomb network

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Abstract

D 3h symmetric hexa-peri-hexabenzocoronene substituted by three carboxylic acid groups (HBC-COOH) was synthesized. HBC-COOH formed a rigid two-dimensional (2D) honeycomb network at a solid–liquid interface via intermolecular hydrogen bonding interactions. Guest molecules such as coronene can fill the cavities of this porous 2D network.

Graphical abstract: Synthesis and self-assembly of a D3h symmetric polycyclic aromatic hydrocarbon into a rigid 2D honeycomb network

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Publication details

The article was received on 16 Dec 2016, accepted on 06 Mar 2017 and first published on 09 Mar 2017


Article type: Paper
DOI: 10.1039/C6NJ03962F
Citation: New J. Chem., 2017, Advance Article
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    Synthesis and self-assembly of a D3h symmetric polycyclic aromatic hydrocarbon into a rigid 2D honeycomb network

    L. Zhang, J. Li, S. Qiu, X. Huang and Z. Zeng, New J. Chem., 2017, Advance Article , DOI: 10.1039/C6NJ03962F

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