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Issue 9, 2017
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Copper porphyrin catalyzed esterification of C(sp3)–H via a cross-dehydrogenative coupling reaction

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Abstract

The crystal structure of 5,10,15,20-tetra(ethoxycarbonyl)porphyrin copper(II) showed that its central copper has a six-coordinate structure. An efficient copper porphyrin-catalyzed cross-dehydrogenative coupling (CDC) esterification reaction between C(sp3)–H and carboxylic acids using di-tert-butyl peroxide (DTBP) as an oxidant was established. The kinetic isotope effect (KIE) indicated that C(sp3)–H bond cleavage was the rate-determining step of this CDC reaction.

Graphical abstract: Copper porphyrin catalyzed esterification of C(sp3)–H via a cross-dehydrogenative coupling reaction

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Publication details

The article was received on 11 Dec 2016, accepted on 28 Mar 2017 and first published on 29 Mar 2017


Article type: Paper
DOI: 10.1039/C6NJ03876J
Citation: New J. Chem., 2017,41, 3508-3514
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    Copper porphyrin catalyzed esterification of C(sp3)–H via a cross-dehydrogenative coupling reaction

    H. Wang, W. Wen, H. Zou, F. Cheng, A. Ali, L. Shi, H. Liu and C. Chang, New J. Chem., 2017, 41, 3508
    DOI: 10.1039/C6NJ03876J

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