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Supported palladium nanoparticles as switchable catalyst for aldehyde conjugate/s and acetate ester syntheses from alcohols

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Abstract

Polymer-supported Pd(0) (Pd@PS) nanoparticles (NPs) were explored as a switchable catalyst for oxidative aldehyde conjugate/s (AC/s) and acetate esters (AEs) syntheses from alcohols. Using the same substrates, the catalyst in the presence of oxygen and K2CO3 participated in AC/s synthesis, and in the presence of traces of air and NaOtBu, unusual AEs products were obtained.

Graphical abstract: Supported palladium nanoparticles as switchable catalyst for aldehyde conjugate/s and acetate ester syntheses from alcohols

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Publication details

The article was received on 02 Dec 2016, accepted on 14 Mar 2017 and first published on 15 Mar 2017


Article type: Letter
DOI: 10.1039/C6NJ03769K
Citation: New J. Chem., 2017, Advance Article
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    Supported palladium nanoparticles as switchable catalyst for aldehyde conjugate/s and acetate ester syntheses from alcohols

    S. Kumar, A. Chaudhary, Bandna, D. Bhattacherjee, V. Thakur and P. Das, New J. Chem., 2017, Advance Article , DOI: 10.1039/C6NJ03769K

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