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Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

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Abstract

A transition metal free, water based, greener protocol for the allylic alkylation, allylic amination, O-allylation of (E)-1,3-diphenylallyl acetate is described. The developed methodology is applicable for a wide range of nucleophiles furnishing excellent yields of corresponding products up to 87% under mild reaction conditions. A distinct effect of water and base is explored for allylic nucleophilic substitution reactions of (E)-1,3-diphenylallyl acetate.

Graphical abstract: Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

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Publication details

The article was received on 17 Oct 2017, accepted on 29 Nov 2017 and first published on 30 Nov 2017


Article type: Paper
DOI: 10.1039/C7GC03123H
Citation: Green Chem., 2018, Advance Article
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    Water promoted allylic nucleophilic substitution reactions of (E)-1,3 diphenylallyl acetate

    S. A. Ghorpade, D. N. Sawant, A. Makki, N. Sekar and J. Eppinger, Green Chem., 2018, Advance Article , DOI: 10.1039/C7GC03123H

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