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Excitation of H2O at plasma/water interface by UV irradiation for elevation of ammonia production

Abstract

Ammonia is well known to be a very important chemical substance for human life. Simultaneously, the conventional ammonia production process needs pure nitrogen and pure hydrogen. Hydrogen has been produced from either liquid natural gas (LNG) or coal. In this study, water is used as direct hydrogen source for ammonia production, thereby obviating the need for catalysts or water electrolysis. We have studied and developed a plasma/liquid interface reaction (P/L reaction) that can be used to produce ammonia from air (nitrogen) and water at ambient temperature and pressure, without any catalysts. In this study, the P/L reaction entails enhanced ultraviolet (UV) irradiation of the surface of the water phase. Nitrogen plasma/water interface reaction locus can produce ammonia. In contrast, the vacuum ultraviolet (VUV) irradiated interface reaction locus produces increase of ammonia. In a spin trap electron spin resonance (st-ESR) experiment, large amounts of atomic H (H●) were produced by UV irradiation, especially by VUV irradiation. The derived H· effectively enhanced the P/L reaction rate.

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Publication details

The article was received on 05 Oct 2017, accepted on 05 Dec 2017 and first published on 06 Dec 2017


Article type: Paper
DOI: 10.1039/C7GC03007J
Citation: Green Chem., 2017, Accepted Manuscript
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    Excitation of H2O at plasma/water interface by UV irradiation for elevation of ammonia production

    T. Sakakura, S. Uemura, M. Hino, S. Kiyomatsu, Y. Takatsuji, R. Yamasaki, M. Morimoto and T. Haruyama, Green Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7GC03007J

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