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Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

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Abstract

The highly efficient eco-friendly synthesis of methanol (44% yield, TONs up to 2.3 × 103) directly from carbon dioxide is achieved by using H2 and the iron(II) scorpionate catalyst [FeCl23-HC(pz)3}] (pz = pyrazol-1-yl) in a solvent- or amine-free mild new protocol.

Graphical abstract: Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(ii) catalyst

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Publication details

The article was received on 03 Jul 2017, accepted on 30 Aug 2017 and first published on 30 Aug 2017


Article type: Paper
DOI: 10.1039/C7GC01993A
Citation: Green Chem., 2017, Advance Article
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    Carbon dioxide-to-methanol single-pot conversion using a C-scorpionate iron(II) catalyst

    A. P. C. Ribeiro, L. M. D. R. S. Martins and A. J. L. Pombeiro, Green Chem., 2017, Advance Article , DOI: 10.1039/C7GC01993A

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