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Ecocatalyzed Suzuki-Miyaura cross coupling of heteroaryl compounds


A biobased EcoPd was developed for the Suzuki cross coupling of heteroaryl compounds. Based on the ability of Eichhornia crassipes to bioconcentrate Pd in its roots, we addressed the transformation of plant-derived Pd metals to green catalysts. The methodology is based on eco-friendly procedures. It allowed for the preparation of a wide range of heterocyclic biaryl and heterocyclic-heterocyclic biaryl compounds, with a low Pd catalyst loading. Eco-Pd was found to have the ideal microstructure to promote complex Suzuki reactions without ligands or additives. For the first time, post-reaction solution was treated by rhizofiltration. Resulting EcoPd has been reused with the same performances. This work has established the ecocatalysis concept as a powerful strategy for Pd sustainability, with the development of homogeneous catalysts that are easily recycled and reused.

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Publication details

The article was received on 07 Jun 2017, accepted on 10 Jul 2017 and first published on 10 Jul 2017

Article type: Paper
DOI: 10.1039/C7GC01672G
Citation: Green Chem., 2017, Accepted Manuscript
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    Ecocatalyzed Suzuki-Miyaura cross coupling of heteroaryl compounds

    G. Clavé, F. Pelissier, S. Campidelli and C. Grison, Green Chem., 2017, Accepted Manuscript , DOI: 10.1039/C7GC01672G

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