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Issue 18, 2017
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An atom-economical protocol for direct conversion of Baylis–Hillman alcohols to β-chloro aldehydes in water

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Abstract

This paper describes an atom-economical strategy for the direct conversion of Baylis–Hillman alcohols to β-chloro aldehydes under metal free conditions with excellent functional group tolerance. The use of stable-nontoxic Oxone as a terminal oxidant along with an inexpensive salt (sodium chloride) as a halogen source and water as the reaction medium makes this chemical synthetic process more viable and environmentally benign contributing towards green chemistry.

Graphical abstract: An atom-economical protocol for direct conversion of Baylis–Hillman alcohols to β-chloro aldehydes in water

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Publication details

The article was received on 18 May 2017, accepted on 10 Aug 2017 and first published on 11 Aug 2017


Article type: Paper
DOI: 10.1039/C7GC01483J
Citation: Green Chem., 2017,19, 4446-4450
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    An atom-economical protocol for direct conversion of Baylis–Hillman alcohols to β-chloro aldehydes in water

    R. Bikshapathi, S. P. Parvathaneni and V. Jayathirtha Rao, Green Chem., 2017, 19, 4446
    DOI: 10.1039/C7GC01483J

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