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Oximes as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes

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Abstract

Oximes have been identified as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes under metal-free conditions. The recovered oxime has been utilised for three trials in the synthesis of urea derivatives without any loss in the yield and efficiency. In addition, this template approach could override the usage of hazardous and less stable isocyanates as substrates.

Graphical abstract: Oximes as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes

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Publication details

The article was received on 16 May 2017, accepted on 02 Aug 2017 and first published on 03 Aug 2017


Article type: Communication
DOI: 10.1039/C7GC01449J
Citation: Green Chem., 2017, Advance Article
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    Oximes as reusable templates for the synthesis of ureas and carbamates by an in situ generation of carbamoyl oximes

    G. C. Senadi, M. R. Mutra, T. Lu and J. Wang, Green Chem., 2017, Advance Article , DOI: 10.1039/C7GC01449J

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