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Issue 17, 2017
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Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

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Abstract

Transition-metal-free base-controlled highly regioselective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from various terminal alkynes has been disclosed. These reactions are efficient, practical and mild with good regioselectivity, excellent functional group tolerance as well as good scalability, which provide general and complementary methods to access multiborylated alkanes from various terminal alkynes.

Graphical abstract: Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

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Publication details

The article was received on 17 Apr 2017, accepted on 03 Jun 2017 and first published on 12 Jun 2017


Article type: Communication
DOI: 10.1039/C7GC01161J
Citation: Green Chem., 2017,19, 3997-4001
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    Base-controlled highly selective synthesis of alkyl 1,2-bis(boronates) or 1,1,2-tris(boronates) from terminal alkynes

    G. Gao, J. Yan, K. Yang, F. Chen and Q. Song, Green Chem., 2017, 19, 3997
    DOI: 10.1039/C7GC01161J

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