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A recyclable AgI/OAc catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

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Abstract

The cyclization of carbon dioxide and propargylic alcohols, especially challenging substrates, were efficiently catalyzed by a green and recyclable AgI/OAc system under atmospheric pressure, which is shown to be the most recyclable system with 20 recycle rounds and has the lowest loading among all the reported recyclable systems that work under atmospheric pressure.

Graphical abstract: A recyclable AgI/OAc− catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

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Publication details

The article was received on 23 Jan 2017, accepted on 13 Apr 2017 and first published on 17 Apr 2017


Article type: Communication
DOI: 10.1039/C7GC00276A
Citation: Green Chem., 2017, Advance Article
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    A recyclable AgI/OAc catalytic system for the efficient synthesis of α-alkylidene cyclic carbonates: carbon dioxide conversion at atmospheric pressure

    Y. Yuan, Y. Xie, C. Zeng, D. Song, S. Chaemchuen, C. Chen and F. Verpoort, Green Chem., 2017, Advance Article , DOI: 10.1039/C7GC00276A

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