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Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

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Abstract

A metal-free amino-acyloxylation of 2-aminostyrene was developed for the synthesis of 3-acyloxyl indolines. In the presence of N,N,N-trimethyldodecan-1-aminium iodide and TBHP, the reaction can be carried out in water smoothly with various carboxylic acids. And for internal alkenes, a stereoselective product was formed.

Graphical abstract: Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

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Publication details

The article was received on 18 Jan 2017, accepted on 15 Feb 2017, published on 16 Feb 2017 and first published online on 16 Feb 2017


Article type: Communication
DOI: 10.1039/C7GC00212B
Citation: Green Chem., 2017, Advance Article
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    Metal-free intramolecular amino-acyloxylation of 2-aminostyrene with carboxylic acid for the synthesis of 3-acyloxyl indolines in water

    L. Liu and Z. Wang, Green Chem., 2017, Advance Article , DOI: 10.1039/C7GC00212B

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