Issue 5, 2017

Photoinduced radical-initiated carboxylative cyclization of allyl amines with carbon dioxide

Abstract

Visible light-promoted CO2 upgrading: a highly efficient and metal-free photochemical method for the carboxylative cyclization of allyl amines with CO2 is reported to prepare perfluoroalkylated oxazolidinones with high efficiency under ambient conditions by using perfluoroalkyl iodides as radical sources.

Graphical abstract: Photoinduced radical-initiated carboxylative cyclization of allyl amines with carbon dioxide

Supplementary files

Article information

Article type
Communication
Submitted
20 Nov 2016
Accepted
16 Jan 2017
First published
16 Jan 2017

Green Chem., 2017,19, 1240-1244

Photoinduced radical-initiated carboxylative cyclization of allyl amines with carbon dioxide

M. Wang, Y. Cao, X. Liu, N. Wang, L. He and S. Li, Green Chem., 2017, 19, 1240 DOI: 10.1039/C6GC03200A

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