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Issue 7, 2017
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Catalytic hydrodeoxygenation of anisole: an insight into the role of metals in transalkylation reactions in bio-oil upgrading

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Abstract

Alkylbenzene was observed during continuous hydrodeoxygenation of anisole in toluene. Besides acidic compositions, metals in catalysts play an important role in the transalkylation reaction during the HDO of anisole. Some metals (e.g. NiMo) that enabled partial hydrogenation could temporarily destroy aromaticity, resulting in a high yield of alkylated products. In addition, a high temperature facilitated transalkylation, while temperatures over 400 °C caused severe aromatic condensation.

Graphical abstract: Catalytic hydrodeoxygenation of anisole: an insight into the role of metals in transalkylation reactions in bio-oil upgrading

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Publication details

The article was received on 20 Nov 2016, accepted on 23 Feb 2017 and first published on 23 Feb 2017


Article type: Communication
DOI: 10.1039/C6GC03198F
Citation: Green Chem., 2017,19, 1668-1673
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    Catalytic hydrodeoxygenation of anisole: an insight into the role of metals in transalkylation reactions in bio-oil upgrading

    H. Wang, M. Feng and B. Yang, Green Chem., 2017, 19, 1668
    DOI: 10.1039/C6GC03198F

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