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Volume 202, 2017
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Polysaccharide-derived mesoporous materials (Starbon®) for sustainable separation of complex mixtures

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Abstract

The recovery and separation of high value and low volume extractives are a considerable challenge for the commercial realisation of zero-waste biorefineries. Using solid-phase extractions (SPE) based on sustainable sorbents is a promising method to enable efficient, green and selective separation of these complex extractive mixtures. Mesoporous carbonaceous solids derived from renewable polysaccharides are ideal stationary phases due to their tuneable functionality and surface structure. In this study, the structure–separation relationships of thirteen polysaccharide-derived mesoporous materials and two modified types as sorbents for ten naturally-occurring bioactive phenolic compounds were investigated. For the first time, a comprehensive statistical analysis of the key molecular and surface properties influencing the recovery of these species was carried out. The obtained results show the possibility of developing tailored materials for purification, separation or extraction, depending on the molecular composition of the analyte. The wide versatility and application span of these polysaccharide-derived mesoporous materials offer new sustainable and inexpensive alternatives to traditional silica-based stationary phases.

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Publication details

The article was received on 05 Feb 2017, accepted on 07 Mar 2017 and first published on 07 Mar 2017


Article type: Paper
DOI: 10.1039/C7FD00056A
Citation: Faraday Discuss., 2017,202, 451-464
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    Polysaccharide-derived mesoporous materials (Starbon®) for sustainable separation of complex mixtures

    V. G. Zuin, V. L. Budarin, M. De bruyn, P. S. Shuttleworth, A. J. Hunt, C. Pluciennik, A. Borisova, J. Dodson, H. L. Parker and J. H. Clark, Faraday Discuss., 2017, 202, 451
    DOI: 10.1039/C7FD00056A

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