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Spontaneous electrification of fluoropolymer-water interfaces probed by electrowetting

Abstract

Fluoropolymers are widely used as coatings for their robustness, water-repellence, and chemical inertness. In contact with water, they are known to assume a negative surface charge, which is commonly attributed to adsorbed hydroxyl ions. Here, we demonstrate that a small fraction of these ions permanently sticks to surfaces of Teflon AF and Cytop, two of the most common fluoropolymer materials, upon prolonged exposure to water. Electrowetting measurements carried out after aging in water are used to quantify the density of ‘trapped’ charge. Values up to of -0.07 and -0.2mC/m^2 are found for Teflon AF and for Cytop at elevated pH. A similar charge trapping process is also observed upon aging in various non-aqueous polar liquids and in humid air. A careful analysis highlights the complementary nature of electrowetting and streaming potential measurements in quantifying interfacial energy and charge density. We discuss possible mechanism of charge trapping and highlight the relevance of molecular scale processes for the long term stability and performance of fluoropolymer materials for applications in electrowetting and elsewhere.

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Publication details

The article was accepted on 12 Dec 2016 and first published on 10 Jan 2017


Article type: Paper
DOI: 10.1039/C6FD00245E
Citation: Faraday Discuss., 2017, Accepted Manuscript
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    Spontaneous electrification of fluoropolymer-water interfaces probed by electrowetting

    A. Banpurkar, Y. B. Sawane, S. M. Wadhai, C. Murade, I. Siretanu, D. van den Ende and F. Mugele, Faraday Discuss., 2017, Accepted Manuscript , DOI: 10.1039/C6FD00245E

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