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Fe, Ru, and Os complexes with the same molecular framework: comparison of structures, properties and catalytic activities

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Abstract

A series of group 8 metal complexes with the same molecular framework, [M(PY5Me2)L]n+ (M = Fe, Ru, and Os; PY5Me2 = 2,6-bis[1,1-bis(2-pyridyl)ethyl]pyridine; L = monodentate ligand), were successfully synthesized and structurally characterized. The spectroscopic and electrochemical properties as well as the catalytic activity for water oxidation of these complexes were investigated.

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Publication details

The article was received on 02 Nov 2016, accepted on 02 Dec 2016, published on 02 Dec 2016 and first published online on 02 Dec 2016


Article type: Paper
DOI: 10.1039/C6FD00227G
Citation: Faraday Discuss., 2017, Advance Article
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    Fe, Ru, and Os complexes with the same molecular framework: comparison of structures, properties and catalytic activities

    M. Yoshida, M. Kondo, M. Okamura, M. Kanaike, S. Haesuwannakij, H. Sakurai and S. Masaoka, Faraday Discuss., 2017, Advance Article , DOI: 10.1039/C6FD00227G

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