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A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

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Abstract

A mesoinic pyridylideneamide ligand (PYA) was synthetized and fully characterized and coordinated to an iridium(III) center. This ligand represents the first example of a mesoionic N-donor ligand. Structural and spectroscopic analysis revealed unique properties which were exploited in chemically driven water oxidation catalysis.

Graphical abstract: A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

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Publication details

The article was received on 03 Dec 2017, accepted on 06 Dec 2017 and first published on 06 Dec 2017


Article type: Communication
DOI: 10.1039/C7DT04555G
Citation: Dalton Trans., 2018, Advance Article
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    A mesoionic nitrogen-donor ligand: structure, iridium coordination, and catalytic effects

    M. Navarro, M. Li, S. Bernhard and M. Albrecht, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04555G

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