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Preparation and Reactivity of Iron Complexes Bearing Anionic Carbazole-Based PNP-Type Pincer Ligands toward Catalytic Nitrogen Fixation

Abstract

Iron–chloride, –dinitrogen, and –methyl complexes bearing anionic carbazole-based PNP-type pincer ligands are designed, prepared and characterized by X-ray analysis. Some iron complexes are found to work as catalysts toward nitrogen fixation under mild reaction conditions.

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Publication details

The article was received on 16 Nov 2017, accepted on 05 Dec 2017 and first published on 06 Dec 2017


Article type: Paper
DOI: 10.1039/C7DT04327A
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Preparation and Reactivity of Iron Complexes Bearing Anionic Carbazole-Based PNP-Type Pincer Ligands toward Catalytic Nitrogen Fixation

    J. Higuchi, S. Kuriyama, A. Eizawa, K. Arashiba, K. Nakajima and Y. Nishibayashi, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT04327A

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