Tuning the dual emissions of a monoruthenium complex with a dangling coordination site by solvents, O2, and metal ions

Si-Hai Wu; Jiang-Yang Shao; Zhong-Liang Gong; Na Chen; Yu-Wu Zhong

doi:10.1039/C7DT04198E

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Tuning the dual emissions of a monoruthenium complex with a dangling coordination site by solvents, O₂, and metal ions†

Si-Hai Wu,*^a Jiang-Yang Shao,^b Zhong-Liang Gong,^b Na Chen^a and Yu-Wu Zhong

*^bc

Author affiliations

* Corresponding authors

^a School of Biomedical Sciences, Huaqiao University, Quanzhou, Fujian 362021, China
E-mail: wusihai@hqu.edu.cn

^b CAS Key Laboratory of Photochemistry, CAS Research/Education Center for Excellence in Molecular Sciences, Institute of Chemistry, Chinese Academy of Sciences, Beijing 100190, China
E-mail: zhongyuwu@iccas.ac.cn

^c University of Chinese Academy of Sciences, Beijing 100049, China

Abstract

A polypyridyl monoruthenium complex with a dangling coordination site shows dual fluorescence/phosphorescence emissions at room temperature. The emission properties can be modulated by multiple stimuli including solvents, O₂, and metal ions.

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Article information

DOI: https://doi.org/10.1039/C7DT04198E
Article type: Communication
Submitted: 07 Nov 2017
Accepted: 24 Nov 2017
First published: 27 Nov 2017

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Dalton Trans., 2018,47, 292-297

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Tuning the dual emissions of a monoruthenium complex with a dangling coordination site by solvents, O₂, and metal ions

S. Wu, J. Shao, Z. Gong, N. Chen and Y. Zhong, Dalton Trans., 2018, 47, 292 DOI: 10.1039/C7DT04198E

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