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Issue 48, 2017
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O2 activation at a trispyrazolylborato nickel(II) malonato complex

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Abstract

To support mechanistic inferences made for an iron-based dioxygenase model, a nickel analogue, i.e. a TpNi-malonate (1) was prepared. 1 proved to represent a rare case of a nickel complex reacting with O2 in a controlled manner – mechanistically different from the iron case – and leads to hydroxylation of the malonate.

Graphical abstract: O2 activation at a trispyrazolylborato nickel(ii) malonato complex

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Publication details

The article was received on 27 Oct 2017, accepted on 19 Nov 2017 and first published on 27 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT04056C
Citation: Dalton Trans., 2017,46, 16792-16795
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    O2 activation at a trispyrazolylborato nickel(II) malonato complex

    S. Hoof, M. Sallmann, C. Herwig, B. Braun-Cula and C. Limberg, Dalton Trans., 2017, 46, 16792
    DOI: 10.1039/C7DT04056C

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