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Constructing CrIII-centered heterometallic complexes: [NiII6CrIII] and [CoII6CrIII] wheels

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Abstract

The solvothermal reaction between Cr(acac)3, MCl2·6H2O (M = Ni, Co) and 2-hydroxy-4-methyl-6-phenyl-pyridine-3-amidoxime (H2L), under basic conditions, led to the synthesis of the heterometallic heptanuclear clusters [MII6Cr(HLzw)6(HL)6]·3Cl (M = Ni, 1; Co, 2), with the nickel analogue displaying an S = 9/2 spin ground-state.

Graphical abstract: Constructing CrIII-centered heterometallic complexes: [NiII6CrIII] and [CoII6CrIII] wheels

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Publication details

The article was received on 27 Oct 2017, accepted on 17 Nov 2017 and first published on 17 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT04043A
Citation: Dalton Trans., 2018, Advance Article
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    Constructing CrIII-centered heterometallic complexes: [NiII6CrIII] and [CoII6CrIII] wheels

    F. E. Kakaroni, A. Collet, E. Sakellari, D. I. Tzimopoulos, M. Siczek, T. Lis, M. Murrie and C. J. Milios, Dalton Trans., 2018, Advance Article , DOI: 10.1039/C7DT04043A

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