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MnAPO-5 as an efficient heterogeneous catalyst for selective liquid phase partial oxidation reactions

Abstract

Heterogeneous catalysis play key role to address the economic and environmental issues of the chemical industry due to their several advantages, like ease of separation, work-up and high recycling efficiency. Herein, we report the synthesis of a robust manganese(IV) incorporated aluminophosphate material (MnAPO-5), with AFI framework topology. The material has been characterized thoroughly by using the powder XRD, XPS, UHR TEM, FE SEM, 31P CP MAS NMR, atomic absorption spectroscopy, UV-Visible spectroscopy and TGA. The Mn-incorporated microporous material has been employed as a heterogeneous catalyst for the oxidation of styrene and synthesis of adipic acid from cyclohexanone in the presence of tert-butyl hydroperoxide (TBHP) as oxidant in air together with high recycling efficiency.

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Supplementary files

Publication details

The article was received on 16 Oct 2017, accepted on 04 Dec 2017 and first published on 05 Dec 2017


Article type: Paper
DOI: 10.1039/C7DT03897F
Citation: Dalton Trans., 2017, Accepted Manuscript
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    MnAPO-5 as an efficient heterogeneous catalyst for selective liquid phase partial oxidation reactions

    S. Chatterjee, P. Bhanja, L. Paul, M. Ali and A. Bhaumik, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT03897F

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