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Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers

Abstract

MII (M = Mn, Ni) coordination frameworks, singly linked by end-on azide ligands, were prepared by employing the long, flexible spacer ligand, p-XBP4. These two-dimensional layer structures underwent reversible crystal-to-amorphous phase transformations upon hydration-dehydration process. Moreover, the magnetic natures change from antiferromagnetic to ferromagnetic coupling when moving from Mn to Ni.

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Publication details

The article was received on 16 Oct 2017, accepted on 06 Dec 2017 and first published on 06 Dec 2017


Article type: Paper
DOI: 10.1039/C7DT03886K
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Reversible crystal-to-amorphous structural transformations and magnetic variations in single end-on azide-bridged MII (M = Mn, Ni) coordination polymers

    C. S. Hong, K. S. Lim, J. H. Song, D. W. Kang, M. Kang, S. Eom and E. K. Koh, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT03886K

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