Issue 48, 2017

Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

Abstract

The organic–inorganic hybrid perovskite (H2hpz)[K(ClO4)3] (H2hpz = diprotonated homopiperazine) exhibits a distinct room-temperature dielectric transition. The dielectric switching at 303 K is associated with an order–disorder transition of the polar guest cation confined in the cage, corresponding to a dynamic change between motional and frozen states.

Graphical abstract: Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

Supplementary files

Article information

Article type
Communication
Submitted
10 Oct 2017
Accepted
07 Nov 2017
First published
07 Nov 2017

Dalton Trans., 2017,46, 16774-16778

Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

Y. Sun, C. Shi and W. Zhang, Dalton Trans., 2017, 46, 16774 DOI: 10.1039/C7DT03798H

To request permission to reproduce material from this article, please go to the Copyright Clearance Center request page.

If you are an author contributing to an RSC publication, you do not need to request permission provided correct acknowledgement is given.

If you are the author of this article, you do not need to request permission to reproduce figures and diagrams provided correct acknowledgement is given. If you want to reproduce the whole article in a third-party publication (excluding your thesis/dissertation for which permission is not required) please go to the Copyright Clearance Center request page.

Read more about how to correctly acknowledge RSC content.

Social activity

Spotlight

Advertisements