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Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

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Abstract

The organic–inorganic hybrid perovskite (H2hpz)[K(ClO4)3] (H2hpz = diprotonated homopiperazine) exhibits a distinct room-temperature dielectric transition. The dielectric switching at 303 K is associated with an order–disorder transition of the polar guest cation confined in the cage, corresponding to a dynamic change between motional and frozen states.

Graphical abstract: Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

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Publication details

The article was received on 10 Oct 2017, accepted on 07 Nov 2017 and first published on 07 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT03798H
Citation: Dalton Trans., 2017, Advance Article
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    Distinct room-temperature dielectric transition in a perchlorate-based organic–inorganic hybrid perovskite

    Y. Sun, C. Shi and W. Zhang, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03798H

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