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Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

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Abstract

The treatment of titanacyclopentadienes with bismuth(III) chloride gave spiro compounds in moderate yields. Two carbon atoms of the diene moiety of the titanacyclopentadiene were connected to one carbon atom of the Cp ligand. This is in sharp contrast to the formation of dihydroindene derivatives, where two carbon–carbon bonds were formed between the diene moiety and the adjacent two carbon atoms of the Cp ligand.

Graphical abstract: Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

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Publication details

The article was received on 09 Oct 2017, accepted on 31 Oct 2017 and first published on 03 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT03789A
Citation: Dalton Trans., 2017, Advance Article
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    Formation of a spiro compound via coupling of a cyclopentadienyl ligand with a diene moiety of titanacyclopentadiene

    M. Bando, Y. Mizukami, K. Nakajima, Z. Song and T. Takahashi, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03789A

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