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Issue 48, 2017
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A wheel-shaped Dy(III) single-molecule magnet supported by polyoxotungstates

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Abstract

A wheel-shaped Dy(III) single-molecule magnet (SMM), supported by polyoxotungstates, Cs15K8Na12[K⊂{(AsW9O33)Dy(H2O)2}6]·71H2O (1), is described here. The polyanion of 1 possesses an idealized S6 symmetry. The effective energy barrier (68 K) obtained from magnetic studies is consistent with the deconvolution of the luminescence spectra of 1.

Graphical abstract: A wheel-shaped Dy(iii) single-molecule magnet supported by polyoxotungstates

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Publication details

The article was received on 04 Oct 2017, accepted on 09 Nov 2017 and first published on 09 Nov 2017


Article type: Paper
DOI: 10.1039/C7DT03721J
Citation: Dalton Trans., 2017,46, 16796-16801
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    A wheel-shaped Dy(III) single-molecule magnet supported by polyoxotungstates

    Y. Huo, Y. Chen, J. Liu, J. Jia, W. Chen, S. Wu and M. Tong, Dalton Trans., 2017, 46, 16796
    DOI: 10.1039/C7DT03721J

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