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Selective and Reversible Adsorption of Cationic Dyes by Mixed Ligand Zn(II) Coordination Polymers Synthesized by Reactants Ratio Modulation

Abstract

Dye capture and separation through coordination polymers (CPs) has been a promising research field in recent times due to the toxic and nondegradable nature of organic dyes released to the environment from various industries as well as the reusability of CPs for the said purpose. Here, we report the synthesis and characterization of two mixed ligand CPs {[Zn2(HBTC)2(L)(H2O)2](C2H5OH)3}n (CP1) and {[Zn5(BTC)2(L)3(OH)4(H2O)2](H2O)4(CH3OH)11}n (CP2), (where, H3BTC = 1,3,5–benzene tricarboxylic acid and L = 1,4–bis(4–pyridyl)–2,3–diaza–1,3–butadiene) by stoichiometry variation of the precursors. Crystal structure revealed that CP1 is a 2D network composed of [Zn2(HBTC)2(H2O)2]n motif linked via terminal nitrogen atoms of L and CP2 is a 3D framework in which symmetrically disposed two dimensional {[Zn5(BTC)2(L)3(OH)4(H2O)2]}n sheets composed of pentanuclear [Zn5(RCO2)6(µ3–OH)2(µ2–OH)2(H2O)2] SBUs are pillared by L ligands. Adsorption and separation of cationic dyes by CP1 and solid–state fluorescence properties of both CPs have been investigated. Cationic dyes (RhB, MB, MV) can be effectively adsorbed by CP1 from their aqueous solution (61%, 90%, and 97%) while anionic dye methyl orange (MO) remains uncaptured. Dye desorption studies and CP1 as a column chromatographic filler for the separation of cationic dyes in water has also been demonstrated.

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Publication details

The article was received on 29 Sep 2017, accepted on 06 Dec 2017 and first published on 06 Dec 2017


Article type: Paper
DOI: 10.1039/C7DT03667A
Citation: Dalton Trans., 2017, Accepted Manuscript
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    Selective and Reversible Adsorption of Cationic Dyes by Mixed Ligand Zn(II) Coordination Polymers Synthesized by Reactants Ratio Modulation

    Y. Rachuri, S. Subhagan, B. Parmar, K. K. Bisht and E. Suresh, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT03667A

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