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Amplification of a metallacyclic receptor out of a dynamic combinatorial library

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Abstract

We present herein the Pt(II)-directed self-assembly in water of a new conformationally flexible N-monoalkyl-4,4-bipyridinium-based ditopic ligand into a library of six different metallacyclic structures. This constitutionally dynamic library can be pushed to increase the production of one of the supramolecules in aqueous media, either by controlling the concentration of the building blocks or upon addition of an appropriate aromatic substrate.

Graphical abstract: Amplification of a metallacyclic receptor out of a dynamic combinatorial library

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Publication details

The article was received on 11 Sep 2017, accepted on 24 Oct 2017 and first published on 24 Oct 2017


Article type: Communication
DOI: 10.1039/C7DT03379F
Citation: Dalton Trans., 2017, Advance Article
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    Amplification of a metallacyclic receptor out of a dynamic combinatorial library

    A. Blanco-Gómez, T. Rama, O. Domarco, I. Neira, V. Blanco, J. M. Quintela, M. D. García and C. Peinador, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03379F

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