Issue 45, 2017
From the journal:

Dalton Transactions

The Cu(i)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates†

Oliver Linnenberg,a   Aleksandar Kondinski,a   Cornelia Stöckera  and  Kirill Yu. Monakhov ORCID logo *a  

* Corresponding authors

a Institut für Anorganische Chemie, RWTH Aachen University, 52074 Aachen, Germany
E-mail: kirill.monakhov@ac.rwth-aachen.de

Abstract

The [V6O13{(OCH2)3CCH2OCH2C[triple bond, length as m-dash]CH}2]2− with two terminal alkyne functionalities exhibits excellent reactivity towards (bio-)organic azides. The designed synthetic protocol for the generation of triazol-modified Lindqvist hexavanadates grants access to bio-“clicked” polyoxometalates with spectroscopically detectable 51V nuclei.

Graphical abstract: The Cu(i)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates

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Article information

DOI
https://doi.org/10.1039/C7DT03376A
Article type
Communication
Submitted
11 Sep 2017
Accepted
21 Sep 2017
First published
22 Sep 2017

Dalton Trans., 2017,46, 15636-15640

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The Cu(I)-catalysed Huisgen 1,3-dipolar cycloaddition route to (bio-)organic functionalisation of polyoxovanadates

O. Linnenberg, A. Kondinski, C. Stöcker and K. Yu. Monakhov, Dalton Trans., 2017, 46, 15636 DOI: 10.1039/C7DT03376A

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