Jump to main content
Jump to site search


Tuning the Flexibility of Interpenetrated Frameworks by Small Difference in Fluorene Moiety

Abstract

[Zn2(FDC)2(bpy)] (LMOF-202) and [Zn2(OFDC)2(bpy)] (LMOF-201) (FDC: fluorene-2,7-dicarboxylate, OFDC: 9-fluorenone-2,7-dicarboxylate, bpy: 4,4’-bipyridine) have the interpenetrated isostructures. However, their gas sorption behaviors indicate that LMOF-202 is rigid, whereas LMOF-201 is flexible. We found that the structural flexibility of LMOF-201 was due to the addition of only one oxygen atom into the ligand.

Back to tab navigation

Supplementary files

Publication details

The article was received on 08 Sep 2017, accepted on 10 Oct 2017 and first published on 10 Oct 2017


Article type: Communication
DOI: 10.1039/C7DT03338A
Citation: Dalton Trans., 2017, Accepted Manuscript
  •   Request permissions

    Tuning the Flexibility of Interpenetrated Frameworks by Small Difference in Fluorene Moiety

    Y. Ma, Y. Harada, A. Hori, Y. Hijikata, L. Li and R. Matsuda, Dalton Trans., 2017, Accepted Manuscript , DOI: 10.1039/C7DT03338A

Search articles by author

Spotlight

Advertisements