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Issue 44, 2017
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Tuning the flexibility of interpenetrated frameworks by a small difference in the fluorene moiety

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Abstract

[Zn2(FDC)2(bpy)] (LMOF-202) and [Zn2(OFDC)2(bpy)] (LMOF-201) (FDC: fluorene-2,7-dicarboxylate, OFDC: 9-fluorenone-2,7-dicarboxylate, bpy: 4,4′-bipyridine) have interpenetrated isostructures. However, their gas sorption behaviors indicate that LMOF-202 is rigid, whereas LMOF-201 is flexible. We found that the structural flexibility of LMOF-201 was due to the addition of only one oxygen atom into the ligand.

Graphical abstract: Tuning the flexibility of interpenetrated frameworks by a small difference in the fluorene moiety

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Publication details

The article was received on 08 Sep 2017, accepted on 10 Oct 2017 and first published on 10 Oct 2017


Article type: Communication
DOI: 10.1039/C7DT03338A
Citation: Dalton Trans., 2017,46, 15200-15203
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    Tuning the flexibility of interpenetrated frameworks by a small difference in the fluorene moiety

    Y. Ma, Y. Harada, A. Hori, Y. Hijikata, L. Li and R. Matsuda, Dalton Trans., 2017, 46, 15200
    DOI: 10.1039/C7DT03338A

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