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A novel 2-D Mn selenidostannate(IV) incorporating high-nuclear Mn clusters with spin canting behavior

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Abstract

A solvothermal reaction of SnCl4·5H2O, Mn and Se in ethanolamine (Hea) yielded a novel 2-D Mn selenidostannate(IV) [Mn7(ea)6(SnSe4)2]n (1), which not only provides the first example of the incorporation of a hepta-nuclear Mn cluster [Mn7(ea)6]8+ into a selenidostannate(IV) framework, but also shows unusual spin canting behavior.

Graphical abstract: A novel 2-D Mn selenidostannate(iv) incorporating high-nuclear Mn clusters with spin canting behavior

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Publication details

The article was received on 07 Sep 2017, accepted on 01 Nov 2017 and first published on 01 Nov 2017


Article type: Communication
DOI: 10.1039/C7DT03331A
Citation: Dalton Trans., 2017, Advance Article
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    A novel 2-D Mn selenidostannate(IV) incorporating high-nuclear Mn clusters with spin canting behavior

    J. Zhou, H. Xiao, H. Zou and X. Liu, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03331A

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