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Magneto-structural correlation of hexakis-dmso cobalt(II) complex

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Abstract

The magnetostructural correlation of the hexakis-dmso cobalt(II) complex, [Co(dmso)6](BPh4)2 (dmso: dimethylsulfoxide), was investigated by single-crystal X-ray diffraction study and magnetic measurements. The magnetic analysis concluded the negative Δ value (H = Δ(L2z − 2/3) + E(L2xL2y) − (3/2)κλL·S + β[−(3/2)κLu + ge SuHu (u = x, y, z)), and this was explained by the tetragonal elongation of the octahedral geometry. The magnetostructural correlation was ascertained by both the angular overlap model calculation and the density functional theory calculation.

Graphical abstract: Magneto-structural correlation of hexakis-dmso cobalt(ii) complex

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Publication details

The article was received on 04 Sep 2017, accepted on 31 Oct 2017 and first published on 31 Oct 2017


Article type: Paper
DOI: 10.1039/C7DT03269B
Citation: Dalton Trans., 2017, Advance Article
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    Magneto-structural correlation of hexakis-dmso cobalt(II) complex

    H. Sakiyama, R. Sudo, T. Abiko, D. Yoshioka, R. Mitsuhashi, M. Omote, M. Mikuriya, M. Yoshitake and M. Koikawa, Dalton Trans., 2017, Advance Article , DOI: 10.1039/C7DT03269B

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