A microporous MOF with open metal sites and Lewis basic sites for selective CO2 capture

Jinjie Qian; Qipeng Li; Linfeng Liang; Ting-Ting Li; Yue Hu; Shaoming Huang

doi:10.1039/C7DT03255B

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A microporous MOF with open metal sites and Lewis basic sites for selective CO₂ capture†

Jinjie Qian,

‡*^a Qipeng Li,

‡^b Linfeng Liang,^c Ting-Ting Li,^d Yue Hu*^a and Shaoming Huang*^a

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* Corresponding authors

^a College of Chemistry and Materials Engineering, Wenzhou University, Wenzhou 325035, P. R. China
E-mail: jinjieqian@wzu.edu.cn, yuehu@wzu.edu.cn, smhuang@wzu.edu.cn
Tel: +86-577-88373064

^b College of Chemistry and Life Science, Zhaotong University, Zhaotong 657000, P. R. China

^c State Key Laboratory of Structure Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, China

^d Research Center of Applied Solid State Chemistry, Ningbo University, Ningbo, P. R. China

Abstract

A robust indium–organic framework (InOF-15) with open metal sites and Lewis basic sites has been successfully synthesized using a quinoline-based dicarboxylic acid. Moreover, it exhibits high IAST selective CO₂ sorption from CO₂/CH₄ and CO₂/N₂ mixtures at 273 K, which has been attributed to the coexistence of OMSs and LBSs with strong synergistic effects.

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Article information

DOI: https://doi.org/10.1039/C7DT03255B
Article type: Communication
Submitted: 02 Sep 2017
Accepted: 02 Oct 2017
First published: 02 Oct 2017

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Dalton Trans., 2017,46, 14102-14106

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A microporous MOF with open metal sites and Lewis basic sites for selective CO₂ capture

J. Qian, Q. Li, L. Liang, T. Li, Y. Hu and S. Huang, Dalton Trans., 2017, 46, 14102 DOI: 10.1039/C7DT03255B

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